Abstract
Stability constants of the ternary palladium(II) complexes of triamine 2,2′:6′,2″-terpyridine (terpy) and some amino acids, peptides, DNA constituents or thiols were determined at 25°C and at constant 0.1moldm−3 ionic strength, adjusted using NaNO3. The coordination sites are pH-dependent. The results show the formation of binuclear species, 210. The speciation diagrams of various complex species were evaluated as a function of pH. Good correlations were found between the stability constants of the complexes and basicity of ligands.
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