Mixed-Ligand Complexation of Zinc and Cobalt(II) Complexonates with Amino Acids in an Aqueous Solution

Abstract

The formation of mixed-ligand complexes in the M(II)–Nta and Ida–L systems (M = Co, Zn; L = His, Orn, Lys, Gly, Im, en), where Ida and Nta are the residues of iminodiacetic and nitrilotriacetic acids, was studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (logK, Δ r G0, Δ r H, Δ r S) of formation for these complexes were determined at 298.15 K and an ionic strength I = 0.5 (KNO3). The most probable pattern of coordination between a complexone and an amino acid in mixed-ligand complexes was revealed.