Abstract
The following mixed aggregates between hexynyllithium BuCCLi and lithium thiocyanate, LiNCS, have been characterized by infrared spectroscopy in the ν (CN) region: the mixed species Li 2(BuCC)(NCS) in tetrahydrofuran and dioxane and all three mixed tetranuclear species L 4(BuCC) 3(NCS), Li 4,(BuCC) 2(NCS) 2, Li 4(BuCC)(NCS) 3 in triethylamine. In the same conditions similar species are formed between PhCLi and LiNCS.
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