Abstract
The observation that the chemical equilibrium between the combustion products of solid propellant samples within static calorimeters is unexpectedly freezing at high temperatures is proved through a general numerical simulation of the isochoric cooling with chemical reactions between the gaseous products. A proprietary, direct linearization method of thermochemical computation is used that enables following any chemical reaction in equilibrium with high convergence. The observed chemical freezing within calorimeters is proved.
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