Abstract
Zero valent iron (ZVI) has been used extensively to control environmental pollution owing to its strong reducibility and low cost. Herein, we evaluate the impact of ZVI (iron scrap and ZVI powder with different scales) on anaerobic digestion (AD) reactor performance improvement and syntrophic relationship stimulation among various microbial groups in the methanogenesis process. In recent studies, ZVI addition significantly enhanced methane and volatile fatty acid (VFA) yields and alleviated excessive acidification, ammonia accumulation, and odorous gas production. Further, we reviewed the changes in enzyme activity and microbial metabolism after the addition of ZVI throughout the reaction process. Certain innovative technologies, such as bioelectrochemical system assistance and combined usage of conductive materials, may improve AD performance compared to the use of ZVI alone, the mechanism of which has been discussed from various viewpoints. Furthermore, the primary technical bottlenecks, such as poor mass transfer efficiency in dry AD and high ZVI dosage, have been illustrated, and syntrophic methanogenesis regulated by ZVI addition can be further studied by conducting theoretical research.
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