Abstract

Ca0.6La0.2667TiO3 ceramics were prepared by conventional and microwave sintering techniques and their sinterability, microstructure, and microwave dielectric properties were investigated in detail for comparison. Densified Ca0.6La0.2667TiO3 ceramics were obtained by microwave sintering at 1350°C for 30 min and by conventional sintering at 1450°C for 4 h. An unusual phenomenon was found that some larger grains (grain size range: 8–10 μm) inclined to assemble in one area but some smaller ones (grain size range: 2–4 μm) inclined to gather in another area in the microwave sintered ceramics. The microwave dielectric properties of Ca0.6La0.2667TiO3 ceramics prepared by microwave sintering at 1350°C were as follows: dielectric constant (ɛr) = 119.6, quality factor (Qf) = 17858.5 GHz, and temperature coefficient of resonant frequency (τf) = 155.5 ppm/°C. In contrast, the microwave dielectric properties of the ceramics prepared by conventional sintering at 1450°C were ɛr = 117.4, Qf = 13375 GHz, and τf = 217.2 ppm/°C.

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