Abstract
Three mono-fluorine substituted porphyrin compouds were synthesized under microwave irradiation. The effects of catalysts and oxidants on the yields of mono-fluorine substituted porphyrins also were investigated. The yields of 5,10,15,20-tetrakis(4-fluorophenyl)porphyrin, 5,10,15,20-tetrakis(3-fluorophenyl)porphyrin, 5,10,15,20-tetrakis(2-fluorophenyl)porphyrin in a use of nitrobenzene in propionic acid were 36%, 30% and 28%, respectively. In addition, the zinc(II) ion incorporation reactions into porphyrins to form the zinc porphyrin complexes have been kinetically investigated in acetic acid.
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