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Microstructure and thermal-infrared performance of Ag/TiN/Al₂O₃ multilayer thin films

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Microstructure and thermal-infrared performance of Ag/TiN/Al₂O₃ multilayer thin films

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  • Conference Article
  • 10.1109/secon.2008.4494262
Multilayer thin film cooling devices (non-reviewed)
  • Apr 1, 2008
  • Z Xiao

Solid state thermoelectric cooling devices have been of current interest for hot-spot thermal management. Cooling hot-spots with high heat flux is becoming one of the most important technical challenges facing today's IC industry. The rising temperature limits device minimization and decreases its lifetime. The thermoelectric effect is the appearance of an electric field along a temperature gradient established in a material. The inverse effect, called the Peltier effect, can be used for refrigeration, which uses electricity to pump heat from the cold end to the hot end. In this paper, we report to fabricate an in-plan solid-state thermoelectric cooling device using multilayered Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> thin films. A solid-state in-plan thin film cooling device has been fabricated using multilayered thermoelectric thin films. Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> multilayer thin films were deposited using e-beam evaporation. Solid antimony (III) telluride and bismuth (III) telluride were evaporated to grow the Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> layers for the Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> multilayer films. Bi, Te, and Se powders were mixed with the ratio of 2:2.7:0.3 and were heated at 700degC under nitrogen and melted into solid Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> . The thermally-grown solid Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> was then evaporated to grow the Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> layer for the Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> multilayer thin film together with the Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> layer using e-beam evaporation. The Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> multilayer thin films have a periodic structure consisting of alternating Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> layers or Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> layers, where each layer is about 10 nm thick. The films were analyzed by XRD, SEM, and AFM. The e-beam-grown Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> multilayered thin film has a resistivity of 7.1times10 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-4</sup> Omegaldrcm and an in-plan Seebeck coefficient of 110 muV/K, and the e-beam-grown Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> multilayered thin film has a resistivity of 1.6times10 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-4</sup> Omegaldrcm and an in-plan Seebeck coefficient of -95 muV/K. An in-plan cooling device was fabricated with the Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> /Bi <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Te <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Se <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> films using the standard integrated circuit (IC) fabrication process; the cooling device is consisted of 2080 pairs of p-type and n-type elements, where each element is 200 mum long and 50 mum wide; pn junction diodes were fabricated as thermometers for the measurement of temperature difference between the two ends of device. Temperature difference was achieved between the hot and cold ends under an applied DC current. The developed in-plan cooling device can be a good candidate for the application of highly-efficient micro- cooling.

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  • 10.1155/2018/9693015
High Reliability and Fast‐Speed Phase‐Change Memory Based on Sb70Se30/SiO2 Multilayer Thin Films
  • Jan 1, 2018
  • Advances in Materials Science and Engineering
  • Dan Zhang + 6 more

Sb70Se30/SiO2 multilayer thin films were applied to improve the thermal stability by RF magnetron sputtering on SiO2/Si (100) substrates. The characteristics of Sb70Se30/SiO2 multilayer thin films were investigated in terms of crystallization temperature, ten years of data retention, and energy bandgap. It is observed that the crystallization temperature, 10‐year data retention, and resistance of Sb70Se30/SiO2 multilayer composite thin films exhibited a higher value, suggesting that Sb70Se30/SiO2 multilayer composite thin films have superior thermal stability. The AFM measurement suggests that the SbSe (1 nm)/SiO (9 nm) multilayer thin films possess a smaller surface roughness (RMS = 0.23 nm). Besides, it was found that the phase‐change time of SbSe (1 nm)/SiO (9 nm) multilayer thin films was shorter than that of GST in the process of crystallization and amorphization.

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  • Cite Count Icon 56
  • 10.1016/j.ceramint.2019.06.266
Large enhancement of energy storage density in (Pb0.92La0.08)(Zr0.65Ti0.35)O3/PbZrO3 multilayer thin film
  • Jun 26, 2019
  • Ceramics International
  • Buwei Sun + 6 more

Large enhancement of energy storage density in (Pb0.92La0.08)(Zr0.65Ti0.35)O3/PbZrO3 multilayer thin film

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  • Cite Count Icon 13
  • 10.1016/0302-4598(94)85004-6
Component analysis of the fast photoelectric signal from model bacteriorhodopsin membranes: Part 1. Effect of multilayer stacking and prolonged drying
  • May 1, 1994
  • Bioelectrochemistry and Bioenergetics
  • Sherie Michaile + 1 more

Component analysis of the fast photoelectric signal from model bacteriorhodopsin membranes: Part 1. Effect of multilayer stacking and prolonged drying

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  • 10.1063/5.0129495
Modulating multiple leakage current mechanisms in the [LaNiO3/Ba0.67Sr0.33TiO3]3 multilayer heterostructure thin films via dielectrics/electrode interface modifications
  • Dec 1, 2022
  • AIP Advances
  • Tong Yu + 4 more

Ferroelectric (FE) multilayer heterostructure films have attracted significant attention due to their superior dielectric performance, which shows increasing opportunities in the application of energy storage capacitors or high-capacitance density systems. However, the leakage current density in FE multilayer heterostructure thin films is closely linked to the thickness of each single FE layer and the number of hetero-structure interfaces. In Pt/[LaNiO3/Ba0.67Sr0.33TiO3]3 (Pt/[LNO/BST]3) multilayer thin films, the dominant leakage current mechanism is Poole–Frenkel (PF) emission at room temperature. The space charge limited current (SCLC) and the co-dominated leakage current mechanism from the PF and Schottky (SC) emissions were observed under higher operating temperatures. After inserting an ultrathin SrTiO3 (STO) layer between the Pt/[LNO/BST]3 multilayer thin films and the top Au electrode, the SCLC region was replaced by an Ohmic region, and the SC emission was not detected in the temperature range of 288–368 K. Moreover, the calculated zero-field energy barriers ϕPF of PF emission are higher than the prepared multilayer thin films without the STO layer. Consequently, the leakage current density of Pt/[LNO/BST]3 thin films showed a significant decrease.

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  • Cite Count Icon 5
  • 10.1016/j.tsf.2012.08.049
Improved dielectric and electrical insulating properties in Pb(Mg1/3Nb2/3)0.62Ti0.38O3 based multilayer ferroelectric thin films
  • Sep 3, 2012
  • Thin Solid Films
  • Dan Zhou + 11 more

Improved dielectric and electrical insulating properties in Pb(Mg1/3Nb2/3)0.62Ti0.38O3 based multilayer ferroelectric thin films

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  • Cite Count Icon 6
  • 10.1080/10584587.2015.1063914
Effect of Gallium Interlayer in ZnO and Al-doped ZnO Thin Films
  • Sep 2, 2015
  • Integrated Ferroelectrics
  • Chawalit Bhoomanee + 5 more

For applications in the field of optoelectronics, zinc oxide (ZnO) based transparent conducting oxide thin films such as aluminium-doped zinc oxide (AZO) have recently received much attention. It is one of the most promising alternative materials to the widely used indium tin oxide (ITO or tin-doped indium oxide) and fluorine-doped tin oxide (FTO). In this work, the ZnO and AZO base thin films were prepared by radio frequency (rf) magnetron sputtering technique using ZnO and AZO (1at%Al) ceramic target. The Ga interlayer films, added in between base thin films (ZnO and AZO), were deposited by evaporation technique. Both ZnO/Ga/ZnO and AZO/Ga/AZO multilayer thin film structures were grown on glass substrates. Then the obtained multilayer structures were annealed in argon (Ar) ambient at 400°C for 1 hr. The morphology, qualitative and quantitative elemental analysis, crystal structure, electrical properties, and optical properties of the multilayer thin films were characterized by field emission scanning electron microscope (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), a four-point probe method and UV-Vis spectroscopy. The results revealed that after annealing treatment, the average transmittance of the both multilayer thin films in visible region was improved due to a decrease in surface roughness resulting in an increase in crystalline surface. Furthermore, the results revealed lower sheet resistance in the AZO/Ga/AZO relative to pure ZnO multilayer base thin films. The significance of the electrical properties of the AZO/Ga/AZO films can be achieved due to local structure of Al site in ZnO and partial diffusion of Ga atoms into the base thin film layers. This indicates that the Ga interlayer in both ZnO/Ga/ZnO and AZO/Ga/AZO multilayer thin films can be used to further improve electrical conductivity without degrading optical transmission.

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  • Cite Count Icon 37
  • 10.1016/j.ceramint.2017.09.240
Enhanced electrical and optical properties based on stress reduced graded structure of Al-doped ZnO thin films
  • Oct 2, 2017
  • Ceramics International
  • Gae Hun Jo + 2 more

Enhanced electrical and optical properties based on stress reduced graded structure of Al-doped ZnO thin films

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  • Cite Count Icon 6
  • 10.1016/j.ceramint.2003.12.061
Characterization of sol–gel derived Pb(Zr 0.3Ti 0.7)O 3/PbTiO 3 multilayer thin films
  • Jan 1, 2004
  • Ceramics International
  • Lingling Sun + 4 more

Characterization of sol–gel derived Pb(Zr 0.3Ti 0.7)O 3/PbTiO 3 multilayer thin films

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  • Cite Count Icon 27
  • 10.1021/acsami.7b06533
Multilayer SnSb4-SbSe Thin Films for Phase Change Materials Possessing Ultrafast Phase Change Speed and Enhanced Stability.
  • Aug 1, 2017
  • ACS Applied Materials &amp; Interfaces
  • Ruirui Liu + 7 more

A multilayer thin film, comprising two different phase change material (PCM) components alternatively deposited, provides an effective means to tune and leverage good properties of its components, promising a new route toward high-performance PCMs. The present study systematically investigated the SnSb4-SbSe multilayer thin film as a potential PCM, combining experiments and first-principles calculations, and demonstrated that these multilayer thin films exhibit good electrical resistivity, robust thermal stability, and superior phase change speed. In particular, the potential operating temperature for 10 years is shown to be 122.0 °C and the phase change speed reaches 5 ns in the device test. The good thermal stability of the multilayer thin film is shown to come from the formation of the Sb2Se3 phase, whereas the fast phase change speed can be attributed to the formation of vacancies and a SbSe metastable phase. It is also demonstrated that the SbSe metastable phase contributes to further enhancing the electrical resistivity of the crystalline state and the thermal stability of the amorphous state, being vital to determining the properties of the multilayer SnSb4-SbSe thin film.

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  • Cite Count Icon 8
  • 10.1007/s11051-013-1516-6
Characterization of stable, electroactive protein cage/synthetic polymer multilayer thin films prepared by layer-by-layer assembly
  • Mar 2, 2013
  • Journal of Nanoparticle Research
  • Koichiro Uto + 5 more

We have fabricated electroactive multilayer thin films containing ferritin protein cages. The multilayer thin films were prepared on a solid substrate by the alternate electrostatic adsorption of (apo)ferritin and poly(N-isopropylacrylamide-co-2-carboxyisopropylacrylamide) (NIPAAm-co-CIPAAm) in pH 3.5 acetate buffer solution. The assembly process was monitored using a quartz crystal microbalance. The (apo)ferritin/poly(NIPAAm-co-CIPAAm) multilayer thin films were then cross-linked using a water-soluble carbodiimide, 1-[3-(dimethylamino)propyl]-3-ethylcarbodiimide. The cross-linked films were stable under a variety of conditions. The surface morphology and thickness of the multilayer thin films were characterized by atomic force microscopy, and the ferritin iron cores were observed by scanning electron microscopy to confirm the assembly mechanism. Cyclic voltammetry measurements showed different electrochemical properties for the cross-linked ferritin and apoferritin multilayer thin films, and the effect of stability of the multilayer film on its electrochemical properties was also examined. Our method for constructing multilayer films containing protein cages is expected to be useful in building more complex functional inorganic nanostructures.

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  • Cite Count Icon 4
  • 10.1088/1361-6641/aa691c
Sb7Te3/Ge multilayer films for low power and high speed phase-change memory
  • May 4, 2017
  • Semiconductor Science and Technology
  • Shiyu Chen + 4 more

Phase-change memory has attracted enormous attention for its excellent properties as compared to flash memories due to their high speed, high density, better date retention and low power consumption. Here we present Sb7Te3/Ge multilayer films by using a magnetron sputtering method. The 10 years’ data retention temperature is significantly increased compared with pure Sb7Te3. When the annealing temperature is above 250 °C, the Sb7Te3/Ge multilayer thin films have better interface properties, which renders faster crystallization speed and high thermal stability. The decrease in density of ST/Ge multilayer films is only around 5%, which is very suitable for phase change materials. Moreover, the low RESET power benefits from high resistivity and better thermal stability in the PCM cells. This work demonstrates that the multilayer configuration thin films with tailored properties are beneficial for improving the stability and speed in phase change memory applications.

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  • Cite Count Icon 14
  • 10.1116/1.4725483
Cooling effect of nanoscale Bi2Te3/Sb2Te3 multilayered thermoelectric thin films
  • Jun 6, 2012
  • Journal of Vacuum Science &amp; Technology A: Vacuum, Surfaces, and Films
  • Mardecial Hines + 4 more

Managing high heat flux is one of the greatest technical challenges the integrated circuit (IC) industry is facing because the rising temperature limits device minimization and decreases its lifetime. In this paper, we report the characterization of the cooling effect of nanoscale Bi2Te3/Sb2Te3 multilayered thin films. The multilayer thin film was prepared with e-beam evaporation, and had 21 layers (5-nm-thick each layer and 105-nm-thick total). A thermoelectric device of the multilayer film, which is sandwiched between a diode temperature sensor and a platinum temperature sensor, was fabricated to measure the cooling effect. A maximum cooling temperature difference of about 3 K was obtained from the film at an applied dc electrical current of 5 mA. The nanoscale multilayer film could be integrated in the IC devices for the application of high-efficiency thermoelectric solid-state cooling.

  • Research Article
  • 10.1149/ma2018-02/30/994
The SiO2 and SiNx Multilayer Thin Film Deposition for Encapsulation of OLED Using a NSi-01 Single Precursor By Peald
  • Jul 23, 2018
  • Electrochemical Society Meeting Abstracts
  • Sang Ick Lee + 5 more

OLEDs (Organic Light-Emitting Diodes) are already being used in many mobile devices and TVs, and the next generation of OLED displays will be flexible and foldable. These foldable and flexible OLED displays tend to reduce the radius of curvature under 2.5R and require excellent encapsulation characteristics at thin thicknesses. To satisfy these requirements, multilayer barrier films are considered to be indispensable for the OLEDs. Unlike a single thin film such as SiO2 and SiNx, which is currently applied, the multi-layer itself can produce an antireflection film effect due to a difference in refractive index of each thin film in laminated thin films, thereby reducing diffuse reflection. Also It is effective for blocking ultraviolet rays and loss stress.[1], [2]. Recently, The ALD (Atomic Layer Deposition) method is used for developing thin film encapsulation technology, due to advantages of self limiting surface reaction and controlling the fraction of reaction. In this paper, SiO2, SiNx and multi-layer thin films were deposited on PEN (polyethylene naphthalate) films by using the NSi-01 single precursor by PEALD (Plasma Enhanced Atomic layer Deposition) technique at low temperature (90℃), and thin film thickness and refractive index were measured using a M2000D Spectroscopic Ellipsometer from Woollam. Also, the WVTR (Water Vapor Transmission Rate) characteristics of the deposited films were confirmed using a MOCON Aquatran 2. The refractive index of the SiO2 and SiNx film was 1.47 and 1.85 respectively, which confirmed the possibility of antireflection effect through the multi-layer thin film. The WVTR characteristics were measured according to the thickness of SiO2 and SiNx film over 100hrs. The both deposited SiO2 and SiNx thin film below 150Å showed poor or breakdown encapsulation property (Fig.1). In order to overcome this, the SiO2 film and SiNx film were stacked in order. The deposited multi-layer film showed excellent WVTR characteristics with a breakdown prevention of encapsulation property at thin thickness. Also, 2 to 3% of the carbon in the deposited SiNx film is expected to lower film stress and maintain the flexibility of the entire film (Fig. 2). [3] From this research, we confirmed the possibility of deposit multi-layer thin film consist of silicon oxide film and nitride film in one chamber using a one precursor by PEALD. Especially, multilayer type thin film deposition suggested the possibility of preventing reflection and water vapor simultaneously. References Hemant Kumar Raut,*a V. Anand Ganesh,a A. Sreekumaran Nairb and Seeram Ramakrishna*acd “Anti-reflective coatings: A critical, in-depth review” Energy Environ. Sci.,3784, 2011S. Chhajed, M. F. Schubert, J. K. Kim, and E. F.Schubert, “Nanostructured Multilayer Graded-indexAntireflection Coating for Si Solar Cells with Broadbandand Omnidirectional Characteristics”, Applied Physics Letters, vol. 93, p. 251108, 2008KwanDo Kim, SeokHee Jang, JongMin Kim* and SangMok Chang, “Characterization of Thin Film Passivation for OLED by PECVD” , Korean Chem. 575, 2012 Figure 1

  • Research Article
  • Cite Count Icon 19
  • 10.1063/1.3074134
Calculation of eddy-current loss in multilayer magnetic films considering displacement current
  • Apr 1, 2009
  • Journal of Applied Physics
  • Di Yao + 1 more

At high frequency, displacement current in dielectric layers of multilayer magnetic thin films becomes significant, and eddy-current loss can be much worse than would be predicted without considering displacement current. Two-dimensional finite-element method simulations were used to study the behavior of eddy-current loss in multilayer thin films from 1 kHz to 1 GHz. A closed-form expression for accurate loss prediction with error less than 10% was developed, and its consistency with experimental measurements on Co–Zr–O/ZrO2 multilayer films was checked.

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