Abstract
Resolution of (±)-2- endo-acetoxy-1,8-cineole by Glomerella cingulata is described. Both (+)-2- endo-acetoxy-1,8-cineole and (−)-2- endo-hydroxy-1,8-cineole could be quantitatively obtained in enantiomerically pure form (yield 50%; e.e. 100%). In addition, the odor differences between the enantiomers are also described. In both compounds (acetoxy and hydroxy), the (+)-enantiomers tended to have more bright, light and sweet odors than their (−)-antipodes.
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