Abstract
Anionic micelles of sodium dodecyl sulfate (SDS) inhibit periodate ion oxidations of dipropyl and dibutyl sulfide (Pr 2 S and Bu 2 S) and of 1-methoxy-4-(methylthio)benzene (ArSMe), but there are residual reactions of micellar-bound sulfides at high [SDS] because IO 4 - is not completely excluded from the micellar surface. Concentrations of IO 4 - at surfaces of SDS micelles can be estimated based on a treatment of ion-micelle Coulombic interactions, and second-order rate constants, k 2 m , at the micellar surfaces can be calculated
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