Mg intercalation properties into open-ended vanadium oxide nanotubes

Abstract

Vanadium oxide nanotubes (VO x -NTs) were obtained as the main product in a sol–gel reaction followed by hydrothermal treatment from V 2O 5 precursors and primary amines. The material has a considerable large distance between the layers (ca. 3.5 nm), a wide inner (15–40 nm) and outer diameter (60–100 nm), and the open tube ends which are favorable for the magnesium ion insertion. VO x -NTs are a new kind of material with a unique nanostructured morphology, which can electrochemically insert/deinsert magnesium ions reversibly from the cyclic voltammogram. AC impedance (EIS) demonstrated that Mg 2+ diffusion into the nanotubes is faster than polycrystalline V 2O 5 during intercalation Mg 2+ into the cathodes. X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction (XRD) results gave the mechanism of Mg 2+ insertion into the nanotubes, however, the specific capacity of the rechargeable magnesium is lower than that of lithium.