Abstract

Methane oxidation to methyl bisulfate at ambient pressure in absorption reactor packed with glass balls in presence of iodine as a catalyst was investigated. The process was performed at temperature 120–130 °C, sulfur trioxide concentration in oleum 16–25 wt.%, catalyst concentration 0.008–0.024 mol dm −3, methane flow: 8.69 cm 3 min −1. The optimal conditions for high ester concentration were defined.

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