Abstract

Copper, manganese and iron phthalocyanines were found to be highly efficient catalysts for aziridination of olefins using [N-(p-tolylsulphonyl) imino] phenyliodinane, Chloramine-T and Bromamine-T as nitrene precursors. [N-(p-Tolylsulphonyl) imino] phenyliodinane was found to be better nitrene donor as compared to the Chloramine-T and Bromamine-T and aromatic substituted olefins were found to be more reactive as compared to the aliphatic alkenes under these conditions.

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