Abstract

The isolation and characterization of tetracarbonyl-2-(acetyl)ferrocenylrhenium and tetracarbonyl-2-(acetyl)ferrocenylmanganese from the reaction of acetylferrocene with methylpentacarbonylrhenium (Ia) and -manganese (Ib) respectively, are reported. In addition tetracarbonyl-2-(dimethylaminomethyl)ferrocenylrhenium has been prepared from dimethylaminomethylferrocene (IV) and Ia, but treatment of IV with Ib results in formation of the novel ferrocenylmethyl(methyl)aminomethylenetetracarbonylmanganese.

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