Abstract
Abstract Reactions of [Ph2PO]M with benzaldehyde gave benzyl benzoate and benzyldiphenylphosphine oxide (3) in the case of M=Na, 3, α-hydroxybenzyldiphenylphosphine oxide, benzyl alcohol, benzoin and benzil in the case of M=MgCl, and 3 in the case of M=ZnCl. Reactions of [Ph2PX]M with p-benzoquinone gave 2,5-dihydroxyphenyldiphenylphosphine oxide or sulfide and p-hydroxyphenyl diphenylphosphinate in the cases X=O, S and M=Li, MgCl, Al, and 1,4-phenylene bis(diphenylphosphinate) or bis(diphenylphosphinothioate) in the cases X=O, S and M=FeCl. The reaction mechanisms have been discussed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
