Abstract
Metal organic complexes as an artificial solid-electrolyte interface (MOC-SEI) have been generated via in situ coordinative polymerization between Zn2+ and organic ligand molecules. Compared to conventional anodes, the MOC-SEI coated anode significantly prolongs the lifespan from 100 h to 1450 h for the Zn||Zn symmetrical cells and increases the reversible capacity up to 160 mA h g-1 after 1100 cycles for the Zn||V2O5 full-cells.
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