Abstract
AbstractHydrothermal reaction of the requisite metal nitrate, carboxycinnamic acid (H2cca), and the long‐spanning dipyridylamide bis(4‐pyridylformyl)piperazine (4‐bpfp) generate crystalline coordination polymers whose topology depends critically on the metal coordination geometric preference. These two new phases were structurally characterized by single‐crystal X‐ray diffraction. {[Cu(cca)(4‐bpfp)]·2.5H2O}n (1) manifests a non‐interpenetrated 6‐connected pcu net based on chain motifs featuring carboxylate‐bridged {Cu2(OCO)2} dinuclear units, with embedded D(5) water molecule chains. {[Ni(cca)(4‐bpfp)(H2O)2]·3H2O}n (2) displays an acentric twofold interpenetrated 4‐connected 66 dia network topology with entrapped R(4)A(1) water molecule rings. Variable temperature magnetic studies performed on 1 revealed very weak antiferromagnetic coupling within its dinuclear units. Thermal properties of these two new materials are also discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
