Abstract
The role of catalysts is extremely important for various organic transformations and the synthesis of organic compounds [...]
Highlights
This special issue is dedicated to contemporary progress of new metal-based catalytic systems for the synthesis of organic compounds
The first article deals with the catalytic carbozincation of 2-alkynylamines, 1-alkynylphosphine and -phosphine sulfides [4]
Selective formations of 2-alkenylamines and 1-alkenylphosphine oxides from 2-alkynylamines and 1-alkynylphosphines are obtained after oxidation with H2O2 in diethyl ether, whereas a mixture of stereoisomers is formed in other solvents
Summary
This special issue is dedicated to contemporary progress of new metal-based catalytic systems for the synthesis of organic compounds. Four research articles address four different areas of metal-based catalytic processes towards the development of organic synthesis. The first article deals with the catalytic carbozincation of 2-alkynylamines, 1-alkynylphosphine and -phosphine sulfides [4]. The EtMgBr and Ti(O-iPr)4-catalyzed reaction of the mentioned compounds with Et2Zn has been studied in various solvents, such as diethyl ether, methylene chloride, hexane, toluene, benzene, and anisole.
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