Mechanically durable and long-term repairable flexible lubricant-infused monomer for enhancing water collection efficiency by manipulating droplet coalescence and sliding

Abstract

Lubricant-infused surfaces have attracted widespread attention due to their excellent liquid and organic solution repellency. On account of their high condensation heat transfer coefficient and low nucleation energy barrier, many lubricant-infused surfaces have been applied in water collection. However, they have a number of shortcomings, such as an unstable lubricating layer, poor mechanical/chemical stability and hard shedding, which severely limit the application of slippery surfaces. In this work, the silicone oil was infused into a superhydrophobic monomer (SHM) to form a flexible lubricant-infused monomer (FLIM) with outstanding sliding ability and omniphobicity for low surface energy liquids. Because the silicone oil is similar to the base molecule, there is a strong interacting force to hold the lubricant layer to the surface of the SHM. In addition, the high viscosity of the silicone oil further strengthens the lubricant layer adhesion. Therefore, the FLIM could resist hot liquid and high shear stress (up to 5000 rpm). In addition, the FLIM substrate possessed a self-similar low surface energy structure, which could endure various physical and chemical damages, such as abrasion, scratching, stretching, strong acid and alkali. Finally, pinned droplets could coalesce into large droplets to slide down its surface, resulting from the strain/release due to the high degree of deformation of the surface, which highly enhanced water/liquid coalescence and collection. The preparation of the FLIM was green and the chemicals involved were inexpensive and environmentally friendly, and thus it can be applied for large-scale water collection.