Abstract

Saline soils usually cannot satisfy the requirements of engineering projects because of their inappropriate geotechnical properties. For this reason, they have always been known as one of the problematic soils worldwide. Moreover, the lack of access to normal water has intensified the use of saline water resources such as seawater in many construction and mining projects. Although cement stabilization is frequently used to improve the engineering properties of saline soils, Portland cement’s usage as a binder is constrained by its negative consequences, particularly on the environment. In this line, the effects of NaCl on the microstructural and mechanical properties of alkali-activated volcanic ash/slag-stabilized sandy soil were investigated in this study. Moreover, the effects of binder type, slag replacement, curing time, curing condition, and NaCl content on the mechanical strength of stabilized soils were examined. In addition, microstructural analyses, including XRD, FTIR, and SEM–EDS mapping tests, were performed to understand the physical and chemical interaction of chloride ions and alkali-activated cements. The results show that alkali-activated slag can be a sustainable alternative to Portland cement for soil stabilization projects in saline environments. The increase in sodium chloride (NaCl) content up to 1 wt.% caused the strength development up to 244% in specimens with 50 and 100 wt.% slag, and adding more NaCl had no significant effect on the strength in all curing conditions. Microstructural investigations showed that the replacement of volcanic ash with slag resulted in the formation of C-S-H and C-A-S-H gels that reduced the porosity of the samples and increased mechanical strength. Furthermore, surface adsorption and chemical encapsulation mechanisms co-occurred in stabilized soil samples containing slag and volcanic ash.

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