Abstract

An enhanced modulus effect has been observed in several composition modulated thin films systems containing short wavelength modulations 0.8–1.0 nm. The foils were produced by vapor deposition using two or three source evaporators. As compared with homogeneous foils of the same average composition, the modulated foils exhibited an appreciable increase (up to 300%) in modulus. The plastic behavior, breaking and microhardness of these foils are also presented as a function of the modulation parameters. Current theories based on electronic and strain effects on the elastic constants of metals are also presented to explain the origin of the supermodulus effect. Interdiffusivities of binary and ternary modulated alloys have been measured from the decay of the x‐ray diffraction satellite intensities produced by the modulation. The stability of concentration waves at various temperatures is also discussed and examples of the determination of spinodal temperatures are given. The effect of loss of coherency and the appearance of screening singularities in the diffusivities are also considered.

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