Measurement of partial charge collection in a soft X-ray optimised backside illuminated CMOS image sensor

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The measurement of the charge collection properties at the back surface of a backside illuminated CMOS image sensor optimised for soft X-ray detection is presented. Further investigation of the CIS221-X at the BESSY-II synchrotron has enabled the properties of the back surface partial charge collection layer to be determined. There is agreement between the measured properties and both existing models inferred from quantum efficiency testing conducted on the detector and other detectors with similar back surface processing. The partial charge collection region, close to the back surface of the detector, has a large impact on the behaviour exhibited by the X-ray detector when observing very soft X-rays. Determination of these effects is an important step towards the use of the CIS221-X for scientific applications.

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Characterisation of a soft X-ray optimised CMOS Image Sensor
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Charge-Collection Efficiency in Back-Illuminated Charge-Coupled Devices
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Displacement damage effects induced by fast neutron in backside-illuminated CMOS image sensors
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BackSide-Illuminated (BSI) CMOS Image Sensors (CISs), with developed performance on quantum efficiency and sensitivity, have been applied for aerospace missions and gradually replaced FrontSide-Illuminated (FSI) CISs. Two types of BSI CISs with different epitaxial layer thicknesses were irradiated by 14-MeV neutron up to 3.40 × 1011 n/cm2 to analyze the degradation induced by neutron irradiation. Dark current, dark current distribution, full well capacity, and spectral response were tested before and after the neutron irradiation and at different annealing time points with various temperatures. The results were analyzed to characterize the degradation introduced by the unique backside passivation layer, and the converse illuminated direction. The interface states induced by displacement damage effects at the backside passivation layer were considered as a novel origin of dark current which was not involved in FSI CISs.

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In this study, a back-side illuminated CMOS image sensor (BSI-CIS) without through-silicon via (TSV) is developed with thin wafer handling combination with ultra-wafer thinning technologies. The CIS wafer is implemented front-side processes then temporarily bonded on a Si carrier by Brewer Science adhesive with ZoneBOND™ technology applied. The ZoneBOND™ technology provides a promising solution for thin wafer handling with temporary bonding, wafer thinning, thin wafer processes, and de-bonding. After thinning, the CIS backside is bonded with glass wafer, and the Si carrier is removed using solvent dipping for de-bonding. The thickness of BSI-CIS without TSV is less than 5μm, which is visible light transparent to meet the back-side illumination requirement. Cu/Sn bumps with 50μm size are formed with the bump height uniformity less than 5% in wafer level. The completed BSI-CIS is then assembled on Si substrate. There are totally 400 bumps in this test vehicle design. The Cu/Ni/Au UBMs on Si substrate bonded with Cu/Sn bumps on CIS is conducted by thermal compression bonding. The wafer-level package of TSV-less BSI-CIS has been successfully developed and demonstrated, stacked module is accomplished and passed 1000 cycles of -55°C~125°C TCT in the paper.

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Backside illuminated CMOS image sensors with a 3D stacked architecture, where the pixel array is attached on top of the logic circuit, was introduced and have just come to the market. Image sensor featuring 3D stacking was realized by connection between the interconnect layers of the top and bottom parts using vertical type through-silicon via (TSV).1 Cu bonding technology for 3D integration has been studied and widely applied.2As Wafer-to-wafer bonding process is now being used widely and matured through the production of Backside illuminated CMOS image sensors, Copper-copper bonding provides an attractive route to 3D stacked image sensor since it creates a strong metal bond and enables vertically electrical connection during the bonding process.Specific pre-bonding surface conditioning is necessary to insure high bonding quality of patterned Cu wafers using Cu-Cu non-thermo compression bonding for wafer-to-wafer 3D stacking. Surface preparations for the hybrid fusion bonding such as removal of Cu oxide, Cu surface protection and optimized CMP planarization patterned Cu surfaces have been studied,3 but the study on plasma condition for hybrid fusion bonding is relatively a few. The work described here is investigating of the plasma-related Cu patterned hybrid surface preparation under different plasma conditions.The main physical mechanisms about Cu-Cu non thermal compression bonding are spontaneous adhesion of hydrophilic surfaces followed by Cu diffusion across the bonding interface when Cu-Cu contact is reached (diffusion bonding) have been previously reported.4 The property of Cu dielectric diffusion barriers used in ULSI is hydrophobic. For the efficient bonding of hydrophobic-hydrophobic layers, surface conversion process is introduced.5 In the case of Cu-patterned hybrid bonding in typical Cu metallization layer in ULSI, Trade-off between dielectric diffusion barrier and Cu cannot be avoidable by surface conversion process.During the Cu-patterned hybrid bonding development, the common electrical failed areas were found.To investigate the failure mechanism, influence of plasma condition on the activation of wafer surface and bonding quality was studied. The wafer surface was examined by X-ray photoelectron spectroscopy (XPS), surface roughness, and observation of differential work function uniformity over a full wafer area caused by plasma-induced charge.6The ChemetriQ NVD inspection system from Qcept Technologies was used to inspect differential work function uniformity.After implementing plasma treatment applied in bonding process, Non-uniformity of a charge map and different plasma influence over a full wafer area were shown, even there was no difference through the AFM analysis. For the optimization of the bonding process, especially plasma process, a method to examine the surface condition in this paper makes it possible to monitor the plasma process and improve bonding process

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