Abstract

Boundary conditions of the liquid–solid interface of micro/nano fluid flow are of great interest, as slippage is linked with decreased drag. However, previous studies have seldom included a systematic analysis of the effect of roughness on the measurement and quantification of slip length. For the measurement of slip length using atomic force microscopy (AFM), which is believed to be the most accurate method, a theoretical description of the drainage of thin liquid films between sphere and surface, with realistic roughness, is yet to be published. This study focuses on the measurement and quantification of slip length on rough surfaces immersed in liquids, based on AFM and laser confocal scanning microscopy. A reformulation of the boundary condition is presented, taking into account the effect of surface roughness. The correction to the effective slip length is analyzed, then surfaces with various degrees of spacing roughness Rsm were fabricated. Quantitative analysis of the effective slip length is presented. Results show that the corrected effective slip length remains constant with increased spacing roughness Rsm of surfaces. The results are discussed for the coagulation process of colloids and measurement of slip lengths on roughness-induced surfaces with AFM.

Highlights

  • At the micro or nano scale, fluid flow is subjected to high drag with decreasing dimensions and increasing surface-to-volume ratio in confined systems

  • It is obvious that boundary conditions at the solid–liquid interface have a direct influence on hydrodynamic drag, as published studies show that boundary slip is believed to inhibit hydrodynamic drag [2,3,4,5]

  • A measurement technique is established to obtain effective slip length on roughness-induced surfaces immersed in oil by using atomic force microscopy (AFM) and laser confocal scanning microscopy

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Summary

Introduction

At the micro or nano scale, fluid flow is subjected to high drag with decreasing dimensions and increasing surface-to-volume ratio in confined systems. Vinogradova [18,19,20] investigated the drainage of a thin liquid film confined between two spheres, where hydrophobic force could apply to obtain slip length by employing Navier’s slip condition for liquid flow near the surface. For the technique using hydrodynamic forces to derive slip length on a rough surface, the measured slip length should be replaced by the effective slip length. Investigating the boundary conditions for the flow of liquids on surfaces with varying spacing roughness can provide a fundamental understanding of the interaction of solid and liquid at interfaces. A measurement technique is established to obtain effective slip length on roughness-induced surfaces immersed in oil by using AFM and laser confocal scanning microscopy.

Experiment
Measurement
Schematic colloidal
Quantitation of Effective Slip Length on the Rough Surface
Schematic
Preparation of Superoleophilic and Superoleophobic Surfaces
CA and CAH Measurement
Morphology
CA and CAH
Superoleophilic Surfaces
Superoleophobic Surfaces
Hydrodynamic forcesFFhydro and
Conclusions
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