Abstract
Liquid-liquid phase equilibria for ternary systems of water + (ethanol/1-propanol) + 1-decyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ([Dmim][NTf2]) were measured at T = 298.15 K and atmospheric pressure. Influences of alcohols with different length of alkyl chain on the liquid-liquid equilibria were revealed by the distribution coefficient and selectivity of the alcohols. The phase diagrams for the ternary systems were classified as Treybal's Type I behavior. The experimental data of ternary liquid-liquid equilibria were correlated by the nonrandom two liquid (NRTL) and the universal quasi-chemical (UNIQUAC) models, in which the interaction parameters were optimized. The values of root-mean-square deviation between the experimental and the calculated data show that those models can correlate the experimental data of the studied systems with good accuracy.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
