Abstract
Matrix isolation IR spectroscopy has been used to isolate and investigate weak hydrogen bonded complexes formed between trichloromethane (CHCl 3, CDCl 3) and acetone and trimethylamine in solid argon at 20 K. The most essential changes are observed in the ν(CH) or ν(CD) stretching vibration regions of the spectra of the bonded trichloromethane. The shifts of the ν(CH) and ν(CD) modes for 1:1 complexes are: 38, 27 and 111 cm −1 for CHCl 3 (CD 3) 2CO, CDCl 3 (CH 3) 2CO and CDCl 3 N(CH 3) 3 complexes respectively. The results show that an influence exerted by the matrix cage is an important factor determining properties of the studied complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
