Mass-production of ZnO nanoparticles by precipitation in a rotating packed bed: effect of zinc salt

Abstract

The effect of three zinc salts (Zn(CH3COO)2, ZnSO4, and Zn(NO3)2) on the size of the precursors of the ZnO nanoparticles that were mass-produced by precipitation in a rotating packed bed was studied. The precursors were formed at a rotational speed of 2000rpm and flow rates of 0.5L/min by precipitation using various zinc salts and NaOH as the precipitant. When zinc salts were Zn(CH3COO)2 and ZnSO4, the smallest precursors were obtained at a Zn2+/OH− molar ratio of 1/2. However, when the zinc salt was Zn(NO3)2, the smallest precursors were obtained at a Zn2+/OH− molar ratio of 1/1. Additionally, various zinc salts yielded different effects of the concentrations of Zn2+ and OH− on the size of the precursors. Experimental results indicate that the smallest precursors for various zinc salts were obtained at a Zn(CH3COO)2 concentration of 0.4mol/L and an NaOH concentration of 0.8mol/L, a ZnSO4 concentration of 0.1mol/L and an NaOH concentration of 0.2mol/L, and a Zn(NO3)2 concentration of 0.2mol/L and an NaOH concentration of 0.2mol/L. ZnO nanoparticles were mass-produced by calcining these precursors at sufficient temperatures for 1h. In this way, the average sizes of the ZnO nanoparticles that were mass-produced using Zn(NO3)2, Zn(CH3COO)2, and ZnSO4 as zinc salts were 98, 136, and 186nm, respectively.