Abstract

Manganese hydrogen phosphate monohydrate, MnHPO4·H2O, a new phase, is synthesized. Its solubility is investigated in the temperature range 35–50°C and pH range 3.4–7.5. Ksp, ΔH0, ΔS0 and ΔG0 for the dissolution are reported. The decrease in solubility with increase in pH is explained as due to a surface coating of insoluble basic phosphate.

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