Abstract
The CALPHAD method is used for the thermodynamic modeling of metastable phase transformations in the Fe–Mo system. The relative thermodynamic stability of metastable α and β Mn-like phases and stable phases of the system are assessed. The Gibbs energy of intermetallic compounds with a homogeneity range is described within the Compound Energy Formalism. The calculated versions of Fe–Mo metastable phase diagrams interpret correctly the phase relationships in high-speed solidification of 63Fe37Mo alloy.
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