Abstract
Diene-dienophile-functionalized Fischer-type carbene complexes containing 2-furfurylamino(2-propenyl)carbene ligands have been prepared from hexacarbonyl tungsten and tricarbonyl(methylcyclopentadienyl)manganese. These complexes are distinctly more reactive towards intramolecular Diels-Alder reactions than their acrylic amide congeners. Their reactivity increases with the electron acceptor capacity of the coligand metal fragment and with increasing steric bulk of the amino group.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
