Abstract
Excitation spectra of divalent vanadium in MgO are reported. An accurate analysis of previously unobserved transitions is presented; the magnetic and vibration-induced electric dipole contributions are discussed; and experimental energies and intensities are compared to computed ones. The role of spin-orbit interaction, Jahn-Teller effect, and nonradiative transitions in determining the shape of the zero-phonon lines are discussed.
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