Abstract

Reaction between [(PMe 2Ph) 2PtB 8H 12] and anti-B 18H 22 in benzene results in intimate cluster fusion to generate [(PMe 2Ph)PtB 26H 26-(PMe 2Ph)] which consists of a nido eleven-vertex {PtB 10} subcluster fused, with a {PtB 2} triangular face in common, to a second nido eleven-vertex {PtB 10} subcluster, which is fused in turn to a nido ten-vertex {B 10} subcluster with a {B 2} edge in common.

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