Abstract
A simple approach is presented whereby omega halogenated fatty acids can be obtained from macrocyclic musk lactones which are industrially available. While providing a secure source of 16-iodo-hexadecanoic acid and 17-iodo-heptadecanoic acid, the scheme allows ready access to a large number of untried fatty acid analogs. Examples presented are 16-iodo-hexadecanoic acid. 16-iodo-7-hexadecenoic acid. 16-iodo-12-oxa-hexadecanoic acid, 15-iodo-pentadecanoic acid, and 15-iodo-12-keto-pentadecanoic acid.
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