Abstract
The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M 2 L]Cl 2 , where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4- tert -butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed with [Cu 2 L]Cl 2 (inhibition) and [Ni 2 L]Cl 2 (enhancement) are explained by different reduction mechanisms.
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