Abstract

Recent advances in nanocrystal doping chemistries have substantially broadened the variety of photophysical properties that can be observed in colloidal Mn 2+-doped semiconductor nanocrystals. A brief overview is provided, focusing on Mn 2+-doped II–VI semiconductor nanocrystals prepared by direct chemical synthesis and capped with coordinating surface ligands. These Mn 2+-doped semiconductor nanocrystals are organized into three major groups according to the location of various Mn 2+-related excited states relative to the energy gap of the host semiconductor nanocrystals. The positioning of these excited states gives rise to three distinct relaxation scenarios following photoexcitation. A brief outlook on future research directions is provided.

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