Abstract

Two new double resonance signals were observed in H2CS using the 10R4 CO2 laser line. Both radio-frequency transitions have been assigned. Their behavior in a magnetic field up to 10.5 kG has been studied. One signal was pumped by the 9P20 laser line and the other two by the 10R4 laser line. A 10R4 signal observed at 15.8 MHz was assigned to the 113.8 yields 113.9 transition in the v6 ground state of H2CS. The other 10R4 signal, which was observed at 202.8 MHz, was assigned to the 112.9 yields 112.10 transition in the excited state. This transition is the first to be reported in an excited vibrational state of the electronic ground state. The frequency of this transition was found to be strongly influenced by Coriolis coupling between the v4 and v6 states.© (1999) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.