Abstract
The sinterability of high‐purity, nanocrystalline Y2O3 without any additives was investigated by spark plasma sintering (SPS) for a combination of low sintering temperatures (850°–1050°C) and low heating rates (2–50°C/min). At a sintering temperature of 950°C and a heating rate of 2°C/min, the SPS yielded a polycrystalline Y2O3 having a relative density of 99% and an average grain size of 190 nm. The Y2O3 bodies sintered at 950° and 1050°C for 1h at the heating rate of 2°C/min exhibited an in‐line transmittance of 6%–46% in a wavelength range of 400–800 nm. A high‐resolution transmission electron microscopy observation and chemical analysis by an energy‐dispersive X‐ray spectrometer revealed that the sintered Y2O3 bodies were single‐phase materials without any grain‐boundary amorphous layer or impurity contamination. An isothermal SPS experiment indicated that the grain‐boundary mobility is significantly enhanced by the SPS. An electron energy loss spectrometry indicated that SPS changed atomic configuration of the grain boundaries. The improved sinterability of Y2O3 is attributed to the enhanced diffusion that arises from defect reactions activated by the SPS.
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