Low temperature Moving Bed Bioreactor denitrification as mitigation measure to reduce agricultural nitrate losses

Abstract

The negative impact of agriculture on the quality of local water streams is widely recognized. Fertilizer residues not taken up by the crops leach into the drainage water and enter the surface water, resulting in eutrophication. Despite various initiatives to prevent this leaching by optimizing fertilizer schemes, the desired effect was not achieved, and the focus has shifted to denitrifying end-of-pipe techniques. Because the available area for installing such treatment systems is often limited, the development of intensified systems is a trend that has emerged recently. In this scope, the main goal of this study was therefore to investigate the suitability of a denitrifying Moving Bed Bioreactor (MBBR) as a low footprint technology, which can compete with conventional technologies. Two parallel lab-scale pilot MBBRs, one at low temperature and one at ambient temperature, were operated for 850 days to investigate the effectiveness and robustness under changing process parameters (hydraulic retention time (HRT), temperature, shutdown). Eventually, the system was scaled up to a full-scale installation and monitored during a full drainage season in the field. The pilot-scale MBBRs achieved removal efficiencies above 90% under optimal conditions (high C/N ratio and minimal HRT of 8 h), even while operating at low temperatures. The robustness of the system was also demonstrated by the immediate start-up after a shutdown period of 220 days. Overall, the full-scale MBBR treated 2910.1 m3 drainage water and removed approximately 59 kg NO3-N. Unfortunately, the average removal efficiency, i.e., 70%, was lower than the lab-scale system, but by intensifying the mixing in the MBBR, improved results were obtained. Nitrite accumulation was furthermore also prevented.