Low-temperature irradiation behavior of uranium–molybdenum alloy dispersion fuel

Abstract

Irradiation tests have been conducted to evaluate the performance of a series of high-density uranium–molybdenum (U–Mo) alloy, aluminum matrix dispersion fuels. Fuel plates incorporating alloys with molybdenum content in the range of 4–10 wt% were tested. Two irradiation test vehicles were used to irradiate low-enrichment fuels to approximately 40 and 70 at.% 235U burnup in the advanced test reactor at fuel temperatures of approximately 65 °C. The fuel particles used to fabricate dispersion specimens for most of the test were produced by generating filings from a cast rod. In general, fuels with molybdenum contents of 6 wt% or more showed stable in-reactor fission gas behavior, exhibiting a distribution of small, stable gas bubbles. Fuel particle swelling was moderate and decreased with increasing alloy content. Fuel particles with a molybdenum content of 4 wt% performed poorly, exhibiting extensive fuel–matrix interaction and the growth of relatively large fission gas bubbles. Fuel particles with 4 or 6 wt% molybdenum reacted more rapidly with the aluminum matrix than those with higher-alloy content. Fuel particles produced by an atomization process were also included in the test to determine the effect of fuel particle morphology and microstructure on fuel performance for the U–10Mo composition. Both of the U–10Mo fuel particle types exhibited good irradiation performance, but showed visible differences in fission gas bubble nucleation and growth behavior.