Abstract
Various metal ions have been solvated by dimethylformamide in the gas phase at conditions very similar to those of the quantum chemical model calculations usually performed for the investigation of ion-solvent interactions. Solvates of Li, Na, K, Zn and Cd have been identified by means of mass spectrometry, whereas Hg was found to give no interaction with the solvent vapour. Some characteristic differences between the behaviour of alkali and transition metals, respectively, allow the postulation of possible different molecular structures of the respective solvates.
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