Abstract

Raman measurements were made on polycrystalline Bi2xPbxSr1:6Ln0:4CuO6 for Ln=fLa,Nd, Sm, Eug with various x and doping states. Our measurements suggest a signi cant Bicontribution to the 118cm1 mode but not to the 70cm1 mode which instead shifts to lowerfrequencies with increasing number of CuO2 layers in the Bi-based family. Shifts in the O(2)Srapical oxygen mode can be attributed to unit cell contraction within experimental error.

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