Local Current Flow in Mixed-Phase Silicon Solar Cells and Correlation to Light-Induced Open-Circuit Voltage Enhancement

Abstract

AbstractWe use conductive atomic force microscopy (C-AFM) to measure the local current flow in the mixed-phase hydrogenated silicon n-i-p solar cell structure without the top ITO contact. The forward biased C-AFM images reveal that for the fully amorphous region the current is very low on the entire surface. However, high current spikes appear in the mixed-phase region, where the current spikes are correlated to the formation of nanocrystallite aggregations with a diameter of ~500 nm. Furthermore, the density of the current spikes increases from the mixed-phase to the substantially nanocrystalline regions. The nanocrystallite aggregation supports our previously proposed parallel-connected two-diode model for Voc drops with crystalline volume fraction and light-induced Voc increase in the mixed-phase solar cells. Adding a 50-nm thick a-Si:H buffer layer between the p and i layers significantly reduces the magnitude of the high current spikes, even the top morphology appears unaffected. This result is also consistent with the previously proposed two-diode model for explaining the carrier transport in the mixed-phase solar cells.