Abstract

Liquid−liquid equilibria for the systems water + benzonitrile + N-methylacetamide and water + benzonitrile + N,N-dimethylacetamide were measured in the temperature range of (288.15 to 328.15) K at atmospheric pressure. Phase diagrams, including binodal curves and tie lines, are reported for both systems at each temperature. The plait point compositions have been calculated by Hand’s method. Enthalpy changes for the transfer of the substituted acetamide from benzonitrile to water are given.

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