Abstract

The theory of linear sweep voltammetry at the tubular graphite electrode for quasi-reversible electrode processes has been developed. A general solution for quasi-reversible reactions, from which the solution for irreversible reactions follows as the limiting case, has been presented. The initial boundary value problem has been solved by changing the convective-difusion differential equations to an integral equation which is solved numerically. The current—potential curves have been calculated theoretically and verified experimentally. The dependence of peak current on velocity has also been studied.

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