Abstract

The objective of the communication is to determine if a linear-driving force (LDF) approximation can be used instead of a more rigorous diffusion-convection on the breakthrough behavior under conditions of nonlinear adsorption with a favorable isotherm. Such an approximation is commonly used in the simulation of fixed-bed adsorption operations and chromatography (Ruthven, 1984). However, its use in simulating process in which intraparticle convection is important has not yet been established

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