Abstract
AbstractThe transport equation for the rotating disk electrode is solved numerically with appropriate boundary conditions for reversible and nonreversible redox reactions. A comparison of the computational mode with experimentel data is presented. The adaption of a steady state under variations of experimental parameters ν (scan rate) and ω (angular frequency of rotation) is investigated. It is shown that a triangular voltage scan can be used to indicate the attainment of a steady state in every zone of the current‐voltage curve.
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