Limited access to oxygen reduces the release of harmful trace elements from submerged alum shale debris

Abstract

Construction and mining activities in acid-producing alum shale regions often produce large volumes of crushed rock. Disposal under groundwater level (e.g., a bog) may minimize oxygen access. In this study, the effect of varying oxygen access on the leaching potential of alum shale was investigated by submerging tunnel construction rock debris in synthetic rainwater under atmospheric (AOC) and low oxygen conditions (LOC) for 52 weeks. The sulphate increase and nitrate decrease in the leachates suggested that pyrite (FeS2) in the alum shale was oxidized, but carbonates originating from calcite dissolution provided sufficient buffering capacity (leachate pH ~7.7 over 52 weeks), resulting in neutral rock drainage. Less available oxygen led to significantly lower production of sulphate and acid from pyrite oxidation, reducing the release of harmful elements. Under LOC, the leaching of Mo, Co, Ni, Zn and Cd was 2–4 times lower than under AOC and the lower buffering requirement diminished the release of Ca as well as divalent cations (Mg, Sr, Mn) likely present as impurities in calcite. Contrastingly, limited pyrite oxidation led to less oversaturation with respect to BaSO4 and lower release of Fe in the LOC leachates. Thus, co-precipitation of 226Ra was inhibited and scavenging of leached V, As and Sb by newly formed Fe(OH)3 was not as dominant as in the AOC systems. Leaching of U was ~20 % higher under LOC likely due to enhanced complexation by dissolved carbonate. In general, element leaching rates were slower under low O2 levels. Characterization of water collected at the disposal site after ~1.2 years of discarding tunnel materials showed that the weathering of debris submerged in the open, water-filled pond occurred similarly to leaching under low oxygen conditions. Overall, these results highlight the importance of minimal oxygen access or anaerobic conditions when acid-producing rock waste is stored under water.