Abstract
The limitations of the different evaluation methods used for liquid-phase oxidation processes in the presence of inhibitors have been investigated using computer simulation techniques. The reaction InH + HROOH has been included in a generally accepted mechanism. According to the calculations the rate of initiation and rate coefficient of the reaction InH + HROOH should be determined based on inhibition-period data rather than on values of initial rates of oxygen consumption. Using the same data set different formulae have been suggested depending on the parameters to be calculated.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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