Abstract
Salt-free polyelectrolyte behaviour which is typically observed at low polymer concentrations for polyelectrolyte aqueous solutions and random ionomer non-aqueous solutions (in polar solvents) (i.e., negative angular dependence of the reciprocal scattering in static light scattering and an appearance of the fast mode in dynamic light scattering) has been observed for monotelechelic ionomer solutions in a polar solvent. This indicates that only single charge (per chain) is sufficient to produce intermolecular electrostatic interactions, which are responsible for such characteristic behaviour. However, the ‘characteristic’ behaviour, which is typically observed at higher concentrations for polyelectrolyte and random ionomer solutions (i.e., large positive apparent radius of gyration in static scattering and appearance of the slow mode in addition to the fast mode in dynamic scattering) has not been observed to date for monotelechelic ionomer solutions. The absence of high-concentration characteristics for the monotelechelic ionomer solutions gives additional insight as to the nature and structure of ‘heterogeneities’ in salt-free polyelectrolyte solutions, which is still controversial.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
