Abstract

Light-induced mechanical response of materials has been extensively investigated and widely utilized to convert light energy into mechanical energy directly. The metallic nanomaterials have excellent photothermal properties and show enormous potential in micromechanical actuators, etc. However, the photo-thermo-mechanical properties of individual metallic nanostructures have yet to be well investigated. Here, we experimentally demonstrate a way to realize light-induced reversible expansion of individual gold nanoplates on optical microfibers. The light-induced thermal expansion coefficient is obtained as 21.4 ± 4.6 ∼ 31.5 ± 4.2 μ·K-1 when the light-induced heating temperature of the gold nanoplates is 240 ∼ 490 °C. The photo-thermo-mechanical response time of the gold nanoplates is about 0.3 ± 0.1 s. This insight into the photo-thermo-mechanical properties of the gold nanoplates could deepen the understanding of the light-induced reversible expansion behavior in nanoscale and pave the way for applications based on this piezoelectric-like response, such as light-driven metallic micromotors.

Highlights

  • Light, as one kind of ideal clean energy, can be used for controlling objects remotely, instantly, and precisely

  • Light-induced mechanical response of various kinds of materials is of significant interest since it provides a new and unexpected way to interact with their environment.[2]

  • Most of works focus on the light-induced shape transformation of metallic nanostructures in colloidal solutions or on a solid substrate under high laser power by measuring the absorption and scattering spectrum or comparing the initial and final shape of the structure with electron microscope.[21,22,23,24,25,26,27,28,29,30,31,32,33,34]

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Summary

Introduction

As one kind of ideal clean energy, can be used for controlling objects remotely, instantly, and precisely. Excitation with low-powered femtosecond optical pulses (i.e. in a non-thermal-equilibrium state) are investigated with the help of X-rays or electron diffraction techniques.[35,36,37,38,39,40,41,42] the photo-thermo-mechanical properties, e.g. the reversible photothermal expansion ability of individual metallic nanostructures in a thermal-equilibrium state, have yet to be well investigated. We experimentally demonstrate a way to realize light-induced reversible expansion of individual gold nanoplates on optical microfibers.

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