Levels of Contamination by Pesticide Residues, Polycyclic Aromatic Hydrocarbons (PAHs), and 5-Hydroxymethylfurfural (HMF) in Honeys Retailed in Europe

Abstract

Honey is consumed worldwide because of its nutritional, therapeutic and medicinal properties. Generally, honey should reach the consumer in a pure form, but it is often contaminated in various ways. Thus, this study was designed to check for the presence of pesticide residues, polycyclic aromatic hydrocarbon (PAH) levels, and the content of 5-hydroxymethylfurfural (HMF) in selected European honeys (26 samples) obtained from shops. The most frequently detected organochlorine pesticide (OCPs) was 4,4’-DDD, which was found in fourteen honey samples. Slovakian rapeseed honey was most polluted due to the presence of eight OCPs. The presence of organophosphorus pesticides (OPs) was detected in all the analysed samples, and at least one OP in each tested sample exceeded the acceptable limit. PAHs were detected in most of the analysed samples. As for PAH4s, benzo[a]pyrene was found in forest honey from Slovakia and in Polish lime tree honey, whereas wild flower honey from the UK contained the highest level of PAH4. The investigated honeys from Spain and France met the requirements for HMF content, while honeys of Slovak, Italian and Polish origin in most cases exceeded the established levels (40 mg/kg).